Waste feedstocks such as waste oils, fish waste, waste egg shells and rendered animal fats are the possible source of feedstocks in biodiesel production. Biodiesel production from waste oils sciencedirect. The aim of this study is to investigate the production of biodiesel from waste vegetable oil wvo characterised by high free fatty acid ffa as feedstock with. It would be wise to collect all wco and transport to picton plant for biodiesel production. Onestep alkaline koh catalytic process was employed in the production of the. Oil from jatropha is an acceptable choice for biodiesel production because it nonedible and can easily grow in harsh. Optimization of biodiesel production from waste cooking oil. Oilseed plants are used for the production of biodiesel through the process called transesterification reaction which is a process by which alcohol reacts with vegetable oil in the presence of. Biodiesel production from waste cooking oil using sulfuric. Waste cooking oil is one of polluting materials which increases with human population. Therefore, the use of waste cooking oil should greatly reduce the cost of biodiesel because waste oil is available at a relatively low price.
Production of biodiesel from high acid value waste cooking. Waste frying oil with high levels of free fatty acids as. Contrary to the singlestep biodiesel production process using transesterification of oils, the use of an enzymaticacidcatalyzed hybrid process is proposed for the production of biodiesel from waste cooking oil in our study. However, communityscale biofuel production enables any enterprise with a canteen and therefore a supply of waste cooking oil to start produce biodiesel. Pretreatment of waste cooking oils for biodiesel production. Production of biodiesel from waste cooking oil internet archive. The environmental issues associated with the use of fossilbased energy sources have informed the search for more sustainable energy alternatives. The palm oil resists low acidity levels, up to ph 4. A comparative study of biodiesel production from waste cooking oil using sulfuric acid twostep and microwaveassisted transesterification onestep was carried out.
Microwaveassisted catalytic transesterification using bao. The current technologies of biodiesel production are based on microemulsion 1, pyrolysis 2. Biodiesel production is based on the transesterification reaction of. Food security biodiesel production has existed over a long period of time. The major goals of this study were to extract the biodiesel from the waste vegetable oil, improve biodiesel properties and train the undergraduate engineering students on the renewable energy systems for their future careers. Biodiesel production from waste oils is an attractive option to produce biodiesel economically, but high free fatty acids ffa in waste oils are a serious bottleneck. However, there are concern that biodiesel from vegetable oil would disturb the food market. A twostep transesterification process acid esterification followed by alkali transesterification was employed to produce biodiesel from high free fatty acids ffa in jatropha curcas and waste cooking oils, and a singlestep transesterifcation process alkali transesterifcation was used for camelina sativa oil conversion.
The current technologies of biodiesel production are. Biodiesel production reduces wastewater by 79% and hazardous waste by 96% one gallon of biodiesel stores enough solar energy to purify 2,000 gallons of seawater to drinking water standards food and fuel biodiesel enhances the worlds protein supply soybeans are the most efficient way to grow protein for the food supply. Therefore, this article analyses a process to treat colombian waste cooking oils, by. Transesterification of waste vegetable oil using anthill as catalyst quantity. The mean crystallite size of mgo nanoparticles is 7. If you continue browsing the site, you agree to the use of cookies on this website. As industrialization and population increases, the need for energy is also increasing. Paper open access aspen hysys simulation for biodiesel production. This involves vegetable or animal fats and oils being reacted with shortchain alcohols typically methanol or ethanol.
Oil which has been used for cooking will required more of the reactive agents and methanol than fresh oil. Quality characteristics of biodiesel produced from used cooking oil. The project, thus, aims at utilizing leftover cooking oil, for a possible conversion of biodiesel. Ethyl alcohol with sodium hydroxide as a catalyst was.
In this work, biodiesel ethyl ester was prepared from waste cooking oil collected from a local restaurant in halifax, nova scotia, canada. Production of waste cooking oil in big cities is a problem for public health in different countries around the world. Microwaveassisted catalytic transesterification using bao and koh was evaluated for the. The production of biodiesel from used cooking oil begins with mixing raw. Optimized production of biodiesel from waste cooking oil. Paper open access aspen hysys simulation for biodiesel. It is alkali catalyzed reaction which involves waste cooking oil, methanol, and potassium hydroxide. The cost of waste cooking oil varies from free to 60% less than raw vegetable oils, depending on the source, availability and quantity. Biodiesel production from waste cooking oil is found to be economically feasible method. However, the problem is the high content of free fatty acids, moisture and solid particles presented in the oil. Several efforts are continuously being made for minimizing the cost of feedstock and in this direction waste cooking oil is found the best candidate as raw material for biodiesel production. Since lipase catalysts are much expensive, the usage of lipase in biodiesel production is. How to make biodiesel using a used cooking oil youtube. F over an electric burner to make the oil easier to pour for filtration.
Pdf biodiesel production from waste cooking oil researchgate. Swot analysis of biodiesel production from waste cooking oil 3. Catalysts used in this process are usually acids, base, and lipase. The use of waste cooking oil as biodiesel feedstock reduces the cost of biodiesel production. But the main problem of using waste cooking oil is the existence of free fatty acid as the by product in transesterification process. The properties of the feedstock were determined using standard astm methods. Biodiesel is a form of diesel fuel derived from plants or animals and consisting of longchain fatty acid esters. In the first step, low value waste cooking oil with high free. Slideshare uses cookies to improve functionality and performance, and to provide you with relevant advertising. Moreover, the price of edible plant and vegetable oils is usually higher than petro diesel. A twostep transesterification process was used to produce biodiesel alkyl ester from high free fatty acid ffa waste cooking oil.
This paper presents a detailed cost analysis for a biodiesel plant with. Cost of biodiesel produced from virgin vegetable oil through transesterification is higher than that of fossil fuel, because of high raw material cost. Collect and filter used cooking oil, and allow unwanted water to settle and drain out. Characterization of biodiesel produced from waste cooking. These includes linseed oil, palm seed oil, waste cooked vegetable oil, sunflower seed oil, cotton seed oil, cooking seed oil and animal fats 7, 8, 9. In the case of waste cooking oil containing high percentage of free fatty acid, alkaline. Preparation of biodiesel for preparation of biodiesel in the lab alkali catalyzed transesterification is to be used. Transesterification and production of biodiesel from waste. Present investigation deals with the utilization of waste cooking oil wco for the production of biodiesel. It is typically made by chemically reacting lipids such as animal fat, soybean oil, or some other vegetable oil with an alcohol, producing a methyl, ethyl or propyl ester unlike the vegetable and waste oils used to fuel converted diesel engines, biodiesel is a dropin biofuel. For example, alkali catalysts are generally preferred. Hence, due to its abundance and low cost, waste cooking oil is going to be used as the raw material of biodiesel production. From the report, biodiesel is one of the future fuel options in the market. Biodiesel production is the process of producing the biofuel, biodiesel, through the chemical reactions of transesterification and esterification.
Optimal design of biodiesel production process from waste. To minimize the biofuel cost, in recent days waste cooking oil was used as feedstock. The alcohols used should be of low molecular weight. Biodiesel production from waste cooking oil free download as powerpoint presentation. Applications of waste cooking oil other than biodiesel. Biodiesel production from waste cooking oil a renewable blend for diesel engines. Along this line, wco can be utilized as a beneficial and viable feedstock for the biodiesel production in hong kong. Biodiesel production from jatropha curcas, waste cooking, and.
Less downstream processing is therefore needed for the mass production of biodiesel from domestic oil and its potential for industrial biodiesel production is higher. Producing biodiesel from wco is one of recycling options. World energy consumption world energy consumption will grow by 28% between 2015 and 2040 renewables are expected to be the fastest growing energy source source. Biodiesel production of waste cooking oil through ultrasound cavitation 293 agriculture based country. Said 2 1 department of thermodynamics and fluid mechanics, 2 department of automotive engineering faculty of mechanical engineering universiti teknologi malaysia, skudai 810 johor, malaysia email. Free fatty acids will increase the time required for heating vegetable oil. Production procedure for biodiesel the refined and waste cooking oil wco were originally sunflower oil, supplied by the catering service of the dicle university. Use a cooking thermometer to monitor the temperature. Biodiesel production from waste oils is an attractive option to produce biodiesel economically, but high free fatty acids ffa in waste oils are a serious bottleneck for the process of transesterification.
This data suggests that large quantities of waste cooking oil are available in hong kong. More and more commercial biodiesel producers are capable of handling multifeedstocks which include soybean oil, used cooking oil, and animal fats, etc. Optimization of biodiesel production from waste cooking oil by magnesium oxide nanocatalyst 1 3 spectra of samples are recorded using thermo scienti. Process to produce biodiesel using jatropha curcas oil jco. Purification of crude glycerol from waste cooking oil. Small scale biodiesel production feasibility report.
Esterification pretreatment of free fatty acid in biodiesel. Thesis, department of chemical engineering royal institute of technology kth stockholm, sweden, 2011. Nanostructured magnesium oxide mgo catalysts were prepared by the coprecipitation method and employed for the transesterification of waste cooking oil using methanol. Biodiesel production from waste cooking oils by immobilized enzyme increased about 20% more than free enzyme. In the above context, in this report economic analyses of the biodiesel production from wco in hong kong with different catalysts are. Di erent sources of raw material used for the production of biodiesel are shown in figure. As crude oil price reach a new high, the need for developing alternate fuels has become acute. Biodiesel production from waste cooking oil using the ultrasonic tubular reactor. Cost analysis for biodiesel production from waste cooking oil. Pdf optimization of biodiesel production from waste.
Apr 19, 2017 in this study, biodiesel was produced using waste cooking oil that was discarded as a waste in the environment. Biodiesel synthesis was performed as transesterification of edible and waste cooking sunflower oil catalysed by free lipase from thermomyces lanuginosus lipolase 100l. The production of biodiesel from waste cooking oil offers economic and environmental solutions along with waste management. Biodiesel, esterification, transesterification, fame fatty acid methyl ester,ffa free fatty. Ethanol is the most used because of its low cost, however, greater. It is clear that utilising waste cooking oil helps solving the environmental problems that associated with the disposal of waste cooking oil.
All reactions are carriedout under atmospheric pressure and 1500 rpm of agitation. A feasible solution is employing as raw material for biodiesel production. Handson training the engineering students on biodiesel. Fish oil extracted from fish waste is one of the potential renewable and nonedible feedstock in biofuel production in. This suitable short video explains precisely how its done, and will help you get good at drive green. Review article recent strategy of biodiesel production from.
Therefore, the present study displays great practical latent to produce renewable fuel. Optimized biodiesel production from waste cooking oil wco. Biodiesel from waste cooking oil linkedin slideshare. The depletion of fossil fuel forces the world to look for alternative ways for energy production. Biodiesel, a nontoxic and biodegradable fuel, has recently become a major source of renewable alternative fuels. Dont use a gas burner for this or any other stage of the biodiesel creation process. Synthesis and characterization of biodiesel from waste. The prices of the raw material oil include costs associated with impurity removal and transportation. Characterization of biodiesel produced from waste cooking oil. Nov 06, 2016 it is prepared from waste vegetable oils and animal fats by transesterification process. Mandatory recycling of waste cooking oil from residential.
The transesterification of waste cooking oil was successfully but biodiesel after. The most common way is the production of biodiesel from waste cooking oil. Since it is renewable and benefit in environmental protection, it. Conversion of waste cooking oil to biodiesel research india. Life cycle assessment of biodiesel production from waste. Phan, biodiesel production from waste cooking oil, elsevier, vol. Mendes,production of biodiesel from corn oil and ethanol by homogeneous alkali catalyzed transesterification, msc. Energy information administration, international energy outlook 2017. Apr 12, 2011 looking for a guide on how to make biodiesel using a used cooking oil. An improvement in biodiesel production from waste cooking oil by. Non oil components of the wco were removed by separation. However, the problem is the high content of free fatty acids, moisture and. Technologies, challenges, and future prospects presents approaches, technologies, and source materials for biodiesel production, as well as socioeconomic and political impacts of biodiesel applications. Optimisation of biodiesel production from waste vegetable oil and.
Biodiesel production from waste cooking oil 27 physical characteristics good, texture and struct ure, are preferable to the level of fertility, as it can be corrected with mineral fertilization. Pour your used oil into a large, clean cooking pot and heat it to 95. Gashaw and others published production of biodiesel from waste cooking oil and factors affecting its formation. Comparison of the biodiesel quality produced from refined. The project also included blending of biodiesel with standard diesel and their properties were tested and compared. Recent strategy of biodiesel production from waste cooking. The study focus on the physical and chemical properties of waste cooking oil wco, transesterification and production of biodiesel from wco. Ways of utilising cooking oil always differ in cooking time, cooking temperature and food items cooked.
Biodiesel can be obtained from oils such as cassava oil, palm oil, and corn oil, but the use of these sources for the production of biodiesel would have a negative impact on food supplies 8. Pdf production of biodiesel from waste cooking oil and. Waste cooking oil wco has been considered a lowcost and renewable feedstock for the production of biodiesel and biobased products if it can be economically and efficiently collected and recycled. Conversion of waste cooking oils into environmentally. Domestic waste cooking oil produced biodiesel with a higher yield and better quality profile than biodiesel from restaurant waste cooking oil. The parameters affecting biodiesel production process such as alcohol to oil molar ratio, catalyst concentration, the presence of tetrahydrofuran thf as a cosolvent, and the volumetric flow rates of.
Free fatty acid ffa and h2o content of the collected uco were initially. There has been an expansion in biodiesel production in the last 10 years. Small scale biodiesel production table of contents 1. Utilization of lipase as a biocatalyst to produce biodiesel has advantages over common alkaline catalysts such as mild reaction conditions, easy product separation, and use of. Conversion of waste cooking oil to biodiesel 11 biodiesel feedstock competes with the use of land for food production. Optimization of biodiesel production from high free fatty. Production of biodiesel from waste vegetable oil via km. Pump the oil into a processor and add a methoxide catalyst. Optimization of biodiesel production from waste cooking. This work investigated the potential of producing biodiesel from waste cooking oil wco collected from eateries and fast food restaurants in awka, anambra nigeria. Biodiesel production from waste cooking oil biodiesel. The transesterification process was implemented to extract the biodiesel, and this process was optimized and standardized by selecting three different parameters. Many studies have reported the production of biodiesel from waste oil feedstock with a few cited here to summarize the advantages and challenges of using waste oils 69.
Review article recent strategy of biodiesel production. Four different processes were carried out using virgin sunflower oil and waste cooking oil as the raw material. Vegetable oil consists edible and nonedible oil, edible oil demand being higher than its domestic production, there is no possibility of diverting these oils for production of biodiesel. The production of biodiesel from waste vegetable oils through its pretreatment followed by transesterification process in presence of methanol was investigated using a km micromixer reactor. Pdf biodiesel production from waste cooking oil in laboratory. Effect of methanol to oil molar ratio on the free and immobilized lipase for biodiesel production. Astm international originally known as the american society for testing and. Bacon grease and other solid greases are not acceptable for biodiesel production since they raise the cloud point and could cause cold weather problems. Nov 21, 20 preparation of biodiesel for preparation of biodiesel in the lab alkali catalyzed transesterification is to be used.
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